ASTM International - ASTM D4875-18

Standard Test Methods of Polyurethane Raw Materials: Determination of the Polymerized Ethylene Oxide Content of Polyether Polyols

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Organization: ASTM International
Publication Date: 1 April 2018
Status: active
Page Count: 7
ICS Code (Thermoplastic materials): 83.080.20
significance And Use:

5.1 Measurements of EO content correlate to polyol reactivity (as related to primary hydroxyl content), linearity of foam rise, and hydrophilicity of the polyol and final product.

scope:

1.1 Test Method A-Proton Nuclear Magnetic Resonance Spectroscopy (1H NMR) measures polymerized ethylene oxide (EO) content of ethylene oxide (EO) propylene oxide (PO) polyether polyols used in flexible polyurethane foams and non-foams. It is suitable for diols initiated from glycols of EO or PO containing EO percentages >5. For triols initiated with glycerol (glycerin) and trimethylolpropane, an uncorrected EO value is obtained since both initiators have protons that contribute to the EO measurement.

1.2 Test Method B-Carbon-13 Nuclear Magnetic Resonance Spectroscopy (13C NMR) measures the polymerized EO content of EO-PO polyether polyols used in flexible polyurethane foams and non-foams. It is suitable for diols and triols made from the commonly used initiators and containing EO percentages >5.

1.3 The values stated in SI units are to be regarded as standard.

1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

Note 1: There is no known ISO equivalent to this standard.

1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

Document History

ASTM D4875-18
April 1, 2018
Standard Test Methods of Polyurethane Raw Materials: Determination of the Polymerized Ethylene Oxide Content of Polyether Polyols
1.1 Test Method A—Proton Nuclear Magnetic Resonance Spectroscopy (1H NMR) measures polymerized ethylene oxide (EO) content of ethylene oxide (EO) propylene oxide (PO) polyether polyols used in...
April 1, 2011
Standard Test Methods of Polyurethane Raw Materials: Determination of the Polymerized Ethylene Oxide Content of Polyether Polyols
1.1 Test Method A—Proton Nuclear Magnetic Resonance Spectroscopy (1H NMR) measures polymerized ethylene oxide (EO) in ethylene oxide-propylene oxide polyethers used in flexible urethane foams and...
July 1, 2005
Standard Test Methods of Polyurethane Raw Materials: Determination of the Polymerized Ethylene Oxide Content of Polyether Polyols
1.1 Test Method A—Proton Nuclear Magnetic Resonance Spectroscopy (1H NMR) measures polymerized ethylene oxide (EO) in ethylene oxide-propylene oxide polyethers used in flexible urethane foams and...
November 10, 1999
Standard Test Methods of Polyurethane Raw Materials Determination of the Polymerized Ethylene Oxide Content of Polyether Polyols
1.1 Test Method A -Proton Nuclear Magnetic Resonance Spectroscopy (1H NMR) measures polymerized ethylene oxide (EO) in ethylene oxide-propylene oxide polyethers used in flexible urethane foams and...
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